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- chiral stationary phrase 手性固定相
- Database of chiral stationary phases for high performance liquid chromatography. 关于稳定态手性物质的高效液相色谱法的数据库。
- Separation of racemic naproxen ester on cellulose-based(CTA) chiral stationary phase. 外消旋萘普生酯在纤维素衍生物手性固定相上的分离
- Title： Separation of racemic naproxen ester on cellulose-based(TA)chiral stationary phase. 关键词：纤维素三醋酸酯;手性固定相;手性拆分;萘普生
- A chiral stationary phase was prepared by coating amylose-tris(phenylcarbamate)(ATPC)onto aminopropylated silica gel. 涂敷直链淀粉-三(氨基甲酸苯酯)(ATPC)于作者自制的球形氨丙基硅胶上,制备了手性固定相。
- A chiral stationary phase( CSP) was prepared by coating amylose tris(3,5 dimethyl phenyl carbamate)( ADMPC) onto aminopropylated spherical silica gel. 涂敷直链淀粉三(,5二甲基苯基氨基甲酸酯)(DMPC)自制的球形氨丙基硅胶上,制备了手性固定相。
- Mixture of chiral enantiomers of ethyl lactate and ethyl pyruvate was separated completely by gas chromatography on chiral stationary phase. 运用气相色谱手性固定相在适宜的色谱操作条件下将丙酮酸乙酯和乳酸乙酯手性对映体完全分离。
- The results show that this chiral stationary phase exhibits good stereoselectivity to the series of racemic sulfoxide enantiomers. 所有测试结果显示：该固定相对这类化合物有较好的分离效果。
- The enantiomeric separation of four acidic drugs and one neutral drug on human serum albumin(HSA) chiral stationary phase was described. 考察了4种酸性药物和1种中性药物对映体在人血清白蛋白手性固定相上的保留行为。
- The prepared polymers were applied as the liquid chromatographic chiral stationary phase to test their resolution ability for racemic carnitine hydrochloride. 将所得聚合物用作高效液相色谱固定相,研究了它们对外消旋卡尼丁盐酸盐的拆分能力。
- Rapid choosing the proper combination of chiral stationary phases and SFC solvent modifier plays a key role for using SFC successfully in preparative scale. 快速筛选手性固定相和调节剂是成功应用超临界流体色谱于制备过程的关键。
- By using high performance liquid chromatography(HPLC)with urea derivative as chiral stationary phase,the separations of amino acid enantiomer have been investigated. 利用脲衍生物型手性色谱柱对氨基酸对映体的拆分进行了研究,并对拆分机理进行了探讨。
- The present paper describes the protocol for the preparation of a home made chiral micro-HPLC system and the chiral packing material with cellulose-based chiral stationary phase. 摘要报道了实验室自制的手性微柱高效液相色谱系统和纤维素类手性填料的制备方法，以及用于对映体分离的应用研究。
- To date, five series of novel chiral stationary phases (CSP) are being marketed.The CSPs derived are also amenable for applications in GC, CE/CEC and SFC. 现在，这五个系列的手性色谱固定相均已投入市场，并同时也应用于气相色谱，毛细管电泳/毛细管电动色谱，超临界色谱等领域。
- The chiral resolution of the two enantiomers of fluro xypyr-meptyl was studied by high-performance liquid chromatography (HPLC) chiral stationary phase. 利用高效液相色谱手性固定相法对氟草烟异辛酯对映异构体进行了拆分研究。
- In this paper, the enantioseparation of naringenin was firstly studied by using CDMPC chiral stationary phase(CSP).The solute obtained was separated successfully. 考察了流动相中不同醇类添加剂种类及浓度对其对映体分离的影响。
- OBJECTIVE To develop a HPLC method for the separation of the enantiomers of tamsulosin hydrochloride using derivatized cellulose and protein chiral stationary phases. 目的研究盐酸坦洛新对映体在纤维素衍生物及蛋白质固定相上的保留行为,优化色谱条件。
- Abstract : The classical method for preparation of covalently boned cellulose derivative chiral stationary phases (CSP) with diisocyanate as spacer was improved. 摘要 ： 改进了用于制备键合型纤维素衍生物手性固定相的传统的二异氰酸酯法。
- The phenol hydroxyl group was considered to playa key role in increasing the differenc of interaction between the two isomers and the chiral stationary phase. 拆分过程为焓驱动，酚羟基对提高二异构体与手性固定相之间的作用差异起关键作用。
- A chiral stationary phase (CSP) was prepared by coating cellulose tris (3,5-dimethylphenyl carbamate) (CDMPC) onto aminopropylated spherical silica gel. 摘要将纤维素-三（3,5-二甲基苯基氨基甲酸酯）(CDMPC)涂敷于自制的球形氨丙基硅胶上，制备了手性固定相。
