Ten calix[4]resorcinarene azo derivatives were synthesized and purified and verified. Their absorptive properties and pK H were studied, too.

• 本文合成、提纯并初步鉴定了十种外向式杯[4]芳烃偶氮衍生物类新试剂,试验了其吸收光谱性质,测定了其酸碱离解常数。