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- Stereoselective oxidoreductions catalyzed by enzymes or whole cells have been widely used for preparation of optically active alcohols and other chiral compounds. 摘要以立体选择性氧化还原酶或其全细胞催化的不对称氧化还原反应已经成为转化光学活性手性醇及其他手性化合物的有效手段。
- stereoselective oxidoreduction 立体选择性氧化还原
- The reaction was found to be highly stereoselective. 此反应表现出高度的立体选择性。
- Production and properties of the stereoselective lipase from the screened P. expansum PED-03 (PEL) were investigated. expansum PED-03脂肪酶(PEL)属于碱性脂肪酶。
- The synthesis and application of vinylic tellurides in stereoselective synthesis of alkenes were reviewed. 综述了近年来烯碲化合物的合成及其在立体选择合成中的应用。
- This Paper has reviewed five-membered cyclic sulfate's synthesis and it's applicationfor stereoselective synthesis. 本文将对五元环硫酸酯化合物的合成及其在有机立体合成中的应用作一综述。
- In this review the stereoselective pharmacodynamics of calciumchannel blockers and chiral drugs are summarized. 本文就以手性药物和钙通道阻滞剂的药效学立体选择性作一综述。
- The controls and optimizations of highly stereoselective reactions of the active organic small- molecules. 3. 3． 杂环化合物的固相合成及组合化学。
- This article reviews recent methods used in organic synthesis for the stereoselective reduction of alkynes to Z or E alkenes. 综述了在有机合成领域中，通过炔烃立体选择性还原制备Z-或E-烯烃的近期方法。
- The title compound(6)was synthesized first by stereoselective epoxidation of bicyclo[3.2.0]hept-2-en-endo and exo-6-ol and then by Collins oxidation. 本文通过对双环[3.;2
- The synthesis and application of vinylic tellurides in stereoselective synthesis of alkenes were reviewed. 49 reference are quoted. 综述了近年来烯碲化合物的合成及其在立体选择合成中的应用。参考文献49篇。
- Menthanol ester of chiral chrysanthemic acid was obtained via stereoselective esterification of the racemic acid, and the result was analyzed by MOPAC. 孟醇与过量外消旋菊酰氯反应表现出非对映异构体选择性,得到了光学活性菊酸的L-孟醇酯。
- HUANG Y Z,SHI L L,YANG J H. Highly stereoselective synthesis of Z,E conjugated diene type sex pheromone[J]. J Org Chem,1987,52:3 558-3 560. 孟宪佐.;马尾松毛虫性信息素的3个活性组分顺、反5;7-十二碳双烯-1-醇及其乙酸酯和丙酸酯的合成[J]
- Optically active ethyl(S)-3-hydroxybutyrate,a useful chiral synthon,was prepared by stereoselective reduction of ethyl acetoacetate of the bread yeast in organic solvent. 利用面包酵母在非水相中不对称还原乙酰乙酸乙酯,制备了光学活性的手性化合物S()-3-羟基丁酸乙酯。
- A stereoselective elimination of propafenone was observed in chinese subjects.Enantiomer/enantiomer interaction in pharmacokinetics and pharmacodynamics was also occurred. 普罗帕酮在人体内消除存在立体选择性，且两对映体产生了药效学上的相互作用。
- This paper reviews briefly recent developments in the regio and stereoselective ring opening of 2,3 epoxy alcohols and their derivatives by a variety of methods. 简要综述了对2，3-环氧醇及其衍生物进行区域及立体选择性开环的各种方法的近期进展。
- The development of exceptionally efficient, stereoselective, and chemoselective reactions that can be applied to a wide range of substrates play key roles. 在此过程中，发展具有立体选择性和区域选择性，能够广泛应用于多种底物的有机化学反应起着关键作用。
- A stereoselective hydrolysis of the racemic naproxen methyl ester by immobilized lipase from Candida rugosa in a low aqueous-organic biphase system was studied. 研究了微水-有机溶剂两相体系中固定化脂肪酶催化的萘普生甲酯的立体选择性水解反应。
- This reviews deals with recent advances in the investigation of ionic liquids applied in the field of chemoselective, regioselective, stereoselective organic reactions. 本文综述了近几年离子液体在化学选择性、区域选择性和立体选择性有机合成中的应用。
- Domestic and abroad examples are introduced to illustrate the research and development status of both biocatalytic oxidoreduction and hydrolase-mediated enantioselective synthesis. 结合国内外实例,分别介绍了生物催化的不对称氧化还原反应和水解酶催化的对映选择性合成两个主要方面的研究与开发动态。
