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- primary isotope effect 一级同位素效应
- We have used the primary deuterium and solvent kinetic isotope effects to determine the relative cleavage timing of the glucose OH1 and CH1 bonds in GOOX. 本论文也利用基质同位素效应与溶剂同位素效应,藉以分析葡萄寡糖氧化酶反应时,葡萄糖CH1与OH1键结断裂的可能顺序。
- By the analysis of the competition experiment, the rate-limiting step and the kinetic isotope effect, the possi-ble reaction mechanism of VNS is described. 分别从硝基芳环的结构、亲核试剂的类型和反应条件三方面讨论了影响VNS定位效应的因素;
- Isotope effect of ion sputtering 离子溅射的同位素效应
- vapour pressure isotope effect (VPIE) 蒸汽压同位素效应
- Measurement of kinetic isotope effects indicated that the rate-limiting step of these reactions is the C(sp 2 )-H bond cleavage. 动力学同位素效应测量表明限速步骤;这些反应是在C(藻2)-八键裂解.
- The authors propose an E 2 elimination mechanism in which the cinchona alkaloid acts as a chiral base in consistency with measured isotope effects. 作者提出了电子二是淘汰机制金鸡生物碱手基地作为衡量符合同位素效应.
- vapor pressure isotope effect (VPIE) [化] 蒸气压同位素效应
- kinetic solvent isotope effect (KSIE) [化] 动态溶剂同位素效应
- Based on density-functional theory (DFT) and density-functional perturbation theory (DFPT) we have discussed systematically the hydrogen isotope effects on the thermodynamic properties of TiX2 (X=H, D, and T) system. 应用基于密度泛函理论(DFT)和密度泛函微扰理论(DFPT)的 PWSCF和PHONONS第一原理计算程序系统研究了TiX2(X=H,D,T)系统热力学特性的同位素效应。
- The decreased activity by 50 fold and the kinetic isotope effects show that CH1 bond cleavage is more rate-limited in the Y429F mutant, consistent with the proposed proton shuttling by Tyr429. 其中Y429F突变株酵素活性下降约50倍,且从其动力学同位素效应结果显示,Y429的突变使CH1键结断裂的速率更受到限制,乃符合Y429作为活性中心碱基之推测。
- Keywords titanium;tritium;activation energy value;isotope effect; 钛;氚;表观活化能;同位素效应;
- The disease is still in its primary stage. 这疾病仍然在初发阶段。
- The little boy left primary school at eleven. 这个小男孩十一岁时小学毕业。
- Sure. We are friends since primary school. 当然,我们从小学就是朋友了。
- I started primary school when I was 5 years old. 我五岁时开始读小学。
- A primary cause of Tom's failure is his laziness. 懒惰是汤姆失败的主要原因之一。
- Primary school teachers use a lot of visual aids. 小学教师使用大量的视觉教具。
- Isotope Effects In Chemistry and Biology 化学与生物学中的同位素效应
- Love and hatred are primary emotions. 爱和恨是基本的情感。