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- The catalyst system and technics for oxidative carbonylation of phenol to diphenyl carbonate (DPC) has been studied. 针对苯酚氧化羰基化合成碳酸二苯酯(DPC)洁净化工过程用催化剂和工艺条件进行了较系统的研究。
- Firstly, the oxidative carbonylation of aniline with thiols mediated by stoichiometric selenium has been investigated. 首先考察了在计量硒作用下苯胺和硫醇的氧化羰基化反应。
- The oxidative carbonylation of phenol to DPC catalyzed by palladium complexes catalyst system (PdCl2+ Cu(OAc)2+ TBAB+ H2BQ) has been studied. 开发出了苯酚氧化羰基化直接合成碳酸二苯酯钯系络合物催化体系：PdCl_2+Cu(OAc)_2+TBAB+H_2BQ；
- The laboratory research work on the synthesis and separation of dimethyl carbonate fromliquid phase oxidative carbonylation process undr static conditions are summarized. 总结了静态条件下甲醇液相氧化羰化合成碳酸二甲酯以及产品分离的研究工作。
- The oxidative carbonylation of methanol and ethanol to asymmetric methyl ethyl carbonate (MEC)catalyzed by CuCl coordinated with Schiff base ligands has been studied. 研究了在甲醇、乙醇温和溶液中,氧化羰化一步合成不对称碳酸甲乙酯(MEC)反应。
- Three methods including phosgenation, transesterification and oxidative carbonylation for synthesizing DPC were introduced.The latter two methods were described in detail. 主要介绍了碳酸二苯酯的三种合成方法,即光气法、酯交换法和氧化羰基化法,其中对酯交换法和氧化羰基化法进行了详细的阐述。
- Kinetics of oxidative carbonylation of methanol was studied using a continuous flow micro-reactor.A novel catalyst, activated carbon supported cuprous chloride, was used for the reaction. 活性碳承载氯化亚铜的触媒于微分反应器进行甲醇氧化羰基化的动力研究。
- methanol oxidative carbonylation 甲醇
- At present,the methods of synthesizing DPC are mainly phosgene,oxidation carbonylation and transesterification. 目前,合成碳酸二苯酯方法有光气法、氧化羰基化法和酯交换法。
- Oxidative Carbonylation of Aniline with Pd Complex-Ionic Liquid Catalyst System 离子液体中钯配合物催化苯胺氧化羰化制苯氨基甲酸甲酯
- The Oxidative Carbonylation of Aniline and Its Derivatives in the Presence of Resin Supported Gold 树脂担载金催化苯胺衍生物氧化羰化制氨基甲酸甲酯
- Oxidative Carbonylation for Dimethyl Carbonate Synthesis in Gaseous Phase over Supported Palladium Catalysts 钯催化气相氧化羰基化合成碳酸二甲酯
- Oxidative Carbonylation of Methanol to Dimethyl Carbonate Catalyzed by Cobalt Pyridine-2-Carboxylate 吡啶-2-羧酸钴催化羰化合成碳酸二甲酯
- Oxidative carbonylation synthesis of diethyl carbonate in vapor phase and at atmospheric pressure 常压气相氧化羰基化合成碳酸二乙酯
- STUDY ON THE THERMODYNAMIC AND CATALYTIC REACTION OF METHYL ETHYL CARBONATE SYNTHYSIS BY OXIDATIVE CARBONYLATION 氧化羰化法合成碳酸甲乙酯热力学及催化性能的研究
- Sol-Gel Entrapped Cobalt Pyridine-Carboxylate and Its Catalytic Performance for Oxidative Carbonylation of Methanol 溶胶-凝胶包埋吡啶羧酸钴及其对甲醇氧化羰化反应的催化性能
- Dimethyl Carbonate Synthesis by Oxidative Carbonylation with Cu-Based Complex Catalyst 铜络合催化剂氧化羰基合成碳酸二甲酯的研究
- Dimethyl carbonate synthesis by oxidative carbonylation with a new Cu-based complex catalyst 新型铜络合催化剂用于羰基合成碳酸二甲酯的工艺过程
- Effect of copper chloride hydroxide on catalytic synthesis of diethyl carbonate by oxidative carbonylation of ethanol 碱式氯化铜对氧化羰基合成碳酸二乙酯催化活性的影响
- Keywords diphenyl carbonate;oxidative carbonylation;supercritical dioxygen;analysis;phenol; 碳酸二苯酯;氧化羰基化;超临界二氧化碳;分析;苯酚;
