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- The research progress on carbonylation reactions of heterocycles (such as epoxides and aziridines) during the last 40 years is reviewed in the presence of transition metal complex catalysts. 综述了近40年来杂环化合物和一氧化碳在金属络合物催化下的羰基化反应,详细讨论了不同类型反应的有关机理,并展望了该领域的研究前景。
- Keywords media of water;olefin monomer;transitional metal complex catalyst;syndiotactic 1;2-polybutadiene;review; 水介质;烯烃单体;过渡金属络合催化剂;间同1;2-聚丁二烯;综述;
- The research advances of the chiral ligands metal complexes catalysts used in asymmetric 1,3-dipolar cycloaddition reactions were reviewed in this paper. 综述了手性配体金属络合物催化剂催化1,3-偶极环加成反应的研究进展。
- metal complex catalyst 金属络合物催化剂
- Ultra high relative molecular mass cross-linked alkene polymer was synthesized by bulk polymerization using metal complex as catalyst and 1,5-hexadiene as cross-linking agent. 以金属配合物为催化剂、1,5-己二烯为交联剂,采用本体聚合法合成了交联超高相对分子质量烯烃类聚合物(简称交联聚合物)。
- Keywords double metal complex catalysts;polyether polyol;unsaturation;polymerization mechanism; 双金属氰化物络合催化剂;聚醚多元醇;不饱和度;聚合机理;
- Vapour phase hydrogenation of furfural was employed to produce 2 methylfuran through a copper ammonia complex catalyst. 采用负载型铜氨络合物催化剂进行糠醛气相加氢制2甲基呋喃。
- It is difficult to state when the first metal complex was discovered. 很难说出是什么时候第一次发现金属配合物的。
- Preparation of tetracarbonyl cobaltate sodium, an important homogeneous complex catalyst, was studied. 用红外光谱和碘量法定性、定量测定了四羰基钴钠均相络合催化剂的物化性能。
- The processing of the component needs the new metal complex surfactant. 这个部件的加工需要金属表面活化剂。
- The kinetic study of the homogenous solution hydrogenation of NBR using Rh Ru bimetallic complex catalyst has been carried out. 以铑 -钌 (Rh -Ru)双金属催化剂对丁腈胶 (NBR)进行均相溶液加氢动力学研究。
- Sodium citrate was used as a complex catalyst for the titanium trichloride to reduce insoluble azo dyes and pigments in acetonitrile-alcohol-water system. 本文提出了在乙腈-乙醇-水混合溶剂中以柠檬酸钠作络合剂,三氯化钛还原非水溶性偶氮染料和颜料。
- double metal cyanide complex catalyst 双金属氰化络合物催化剂
- ecent progress is reviewed in synthesis of water soluble phosphine and transition metal complex catalysts as well as their applicanon to catalytic reactions in the aqueous/organic solvent system. 综述了水溶性膦配体的合成，以及水溶性过渡金属络合物催化剂在水／有机两相反应体系中催化剂反应的近期进展。
- Acid dyes and metal complex dyes are used on dyeing wool, polyamide fibers, silks. 酸性染料和金属络合物染料适用于染羊毛,聚酰胺类面料,丝绸等。
- A research is conducted for the biodegradation of metal complex dyes(MCD) by white rot fungi(WRF). 针对白腐菌的特性和独特的降解机理 ;用Coriolusversicolor和Panusconchatus两种典型白腐菌降解金属络合染料 .
- Trimethylaluminum(TMA),usually used in organic catalysis and organic synthesis,was synthesized by reaction of triethylaluminium (TEA) with methyl bromide on iron-stibonium complex catalyst. 用新的催化体系(铁-锑复合催化剂)催化三乙基铝(TEA)与溴甲烷进行烷基交换反应合成三甲基铝(TMA)。
- Polymetallicacetate is a kind of polynuclear metal complex with aluminum and thulium. 该多金属醋酸盐是一种含铝和稀土的多核金属配合物。
- The oxidative carbonylation of phenol to DPC catalyzed by palladium complexes catalyst system (PdCl2+ Cu(OAc)2+ TBAB+ H2BQ) has been studied. 开发出了苯酚氧化羰基化直接合成碳酸二苯酯钯系络合物催化体系：PdCl_2+Cu(OAc)_2+TBAB+H_2BQ；
- A research was conducted for two kind of WRF used to decolor to the sythatic waste liquid of metal complex dyes. 结果表明,实验用菌可对溶剂型金属络合染料起明显的脱色作用,经驯化的白腐真菌处理染料液72小时脱色率高达90%25以上。
