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- Carbosilane dendrimer with allyl end groups is bonded to silicagel.Reactions between the dendrimers and acid-processed silicagel take place with toluene reflux and organic base as catalyst. 含有烯丙基末端基的第二代硅碳烷树枝状大分子与硅胶在甲苯回流及有机碱作酸吸收剂下进行反应。
- Starting from a core molecule possessing alkenyl groups and repeating the hydrosilylation step and alkenylation step, a carbosilane dendrimer with Si-atoms as branching pointing was obtained. 从一个含有烯基的中心核分子开始,重复进行硅氢化作用和烯基化作用的过程可以获得以硅原子作为支化点的碳硅烷树形分子。
- Carbosilane dendrimers 树枝状碳硅烷
- Synthesis and characterization of a new liquid crystalline carbosilane dendrimer 新型树枝状硅碳烷液晶大分子的合成与表征
- Keywords carbosilane dendrimer;silicagel;stationary phase;comprehensive experiment; 关键词硅碳烷树状大分子;硅胶;固定相;综合实验;
- Photoresponse Behaviour of a New Photochromic Liquid Crystalline Carbosilane Dendrimer of the First Generation Containing Hexyloxyazobenzene Moieties Groups in Its Periphery 端基含己氧基偶氮苯基元的一代光致变色液晶碳硅烷树状物的光响应行为研究
- These carbazole dendrimers exhibited good thermal stability. 这些树状化合物都有很好的热稳定性。
- carbosilane liquid crystalline dendrimers (LCD) 硅碳烷液晶树状物(LCD)
- Carbosilane dendrimer 树状硅碳烷
- This paper summarized that different branches of core and ramification had been applied to the synthesis of dendrimers. 本文综述了不同引发核及其衍生物在树枝状大分子合成中的应用。
- The dendrimers of amino as end group have no visbreaking effect on the crude oil. 端基为氮基的树状大分子对原油不具有降黏效果。
- The results show that the dendrimers of ester as end group have visbreaking effect on the crude oil. 5代树状长链酯对原油的降黏性能,分析了树状大分子的端基结构对原油降黏性能的影响。
- We adopted biphenyl as a core, dendrimers containing with 1, 2, 5, and 10 carbazole groups as dendrons have been successfully synthesized. 我们采用联苯作为核心,成功地合成含1、2 、5和10 个咔唑作为树枝化基元的哑铃型树状化合物。
- RESULTS First generation dendrimers which contain two or three ibuprofen on the surface of the branches were synthesized and confirmed by 1HNMR and MS. 结果制备得到外围分支含有两个和三个布洛芬官能基的第一代树枝状化合物,产物经1HNMR和MS确证化学结构。
- If a small amount of these dendrimers is spread, they form an extremely thin molecular film, only one molecule thick (a monolayer). 如果少量的这样的高聚物被铺展开来的话,会形成单分子层薄膜。在洗涤剂里加少许即可大大增加其洗涤效果。
- OBJECTIVE To synthesize ibuprofen-functional dendrimers which and contain a potential group for attaching to targeting molecular. 摘要目的合成外围分支含多个布洛芬官能基团的树枝状化合物。
- In another strategy, using 1,8-naphthalimide as a focal point, we synthesized compounds 29 and 30 as yellow light emitting dendrimers. 另外一个合成的策略是利用1,8-萘二甲醯亚胺作为焦点,我们合成出了放出黄光树状化合物(29)及(30)。
- Dendrimers as drug carriers and their applications to the areas of antiviral, anti-tumor, peptide and saccharide analogues are discussed. 简要综述了树枝状化合物作为药物载体及其在抗病毒、抗肿瘤以及多肽和糖模拟物等领域的研究进展。
- A promising application of dendrimers is that they can be used as high-loading supports for organic synthesis and catalysis. 作为一类新型的高负载量载体应用于有机合成和催化是树状大分子重要的应用领域之一。
- Dendrimers are hyperbranched,monodisperse and three dimensional macromolecules,which consist of an apolar core and polar shell have been referred to as "unimolecular micelles". 树状大分子是一类高度枝化的单分散性大分子,其内部结构呈疏水性,外表面呈亲水性,可称为"单分子胶束"。