We also found that the ratio of relaxation time of the backbone CH to - CH2 - pro-tons can be used to characterize the dynamics of copolymer gels. The correlation between NMR relaxation time T1 and the mean pore radius of gels has been discussed .

 
  • 聚合物主链质子T1与水质子的T1弛豫行为相反,随交联度加大主链运动受限加强而使其运动减慢,反映了聚合物主链的大分子运动特征,发现主链(-CH-)与(-CH2-)质子T1之比可表征凝胶内部分子链运动的强弱; 讨论了NMR弛豫与凝胶孔径结构的关联。
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