The value of activation energy obtained from Kissinger plots is a bit larger than that obtained from Doyle plots due to the change of the crystallized volume fraction at the specific temperature for different heating rates.

 
  • 采用Kissinger曲线计算晶化激活能,由于特征温度在不同的加热速度下对应的晶化体积分数发生变化,从而导致了激活能计算值的偏大。
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