The paper studies synthetical methods as well as principles of stereoselection with Grignard Reaction catalysts of transitional metal compounds, such as Pd, Cu, Ni, Fe, Ti, during the recent decade.

• 简述了近十年来用过渡金属配合物(如钯、铜、镍、锆、铁、钛)作催化剂,通过格氏试剂反应进行立体选择性合成的方法和原理。