Some novel six-coordination zinc complexes formed by the axial coordination of imidazolyl tailed porphyrinatomanganese to porphyrinatozinc were observed from electrospray mass spectra.

• 超分子闭合型构象和卟啉环上拉电子取代基的电子效应都有利于以氢键或配位键驱动的超分子构建。