Phosphine ligands and phosphite ligands for hydroformylation of olefin were reviewed,and some representative ligands and theories were summarized.

• 综述了烯烃氢甲酰化反应中所应用的膦和亚磷酸酯两大类配体,其研究经历了单磷、双磷及单磷配体再度兴起的过程。