It is found that conversion of cyclohexane with NO2 as nitrating agent occurred in a glass reactor at atmospheric pressure.The main product was nitrocyclohexane which was identified by GC-MS.

• 摘要常压下以二氧化氮为硝化剂在玻璃管式反应器中可使环己烷转化，气-质联用分析确证其产物主要是硝基环己烷。