In this review the recent advances in this field are summarized and the catalysts using C, N, P and S as the nucleophilic center are surveyed.

• 摘要总结了近几年来经过极性反转的有机催化的研究近展，概括了以C，N，P，S为中心的各种亲核催化剂的催化机理及催化性能。