In the present work,the density functional theory(DFT) is employed to study the mechanism of the asymmetrical annular-addition of methylenecyclopropanes(MCPs) with 1,3-dicarbonyl compound radicals.

• 用密度泛函方法(DFT)研究了亚甲基环丙烷与1,3-双羰基化合物自由基不对称环加成反应的机理。