For H_2O such local mode phenomena is due to the strong unharmonic of potential energy.For H_2O_2, besides unharmonic, it is further due to a complicate coupling between these two OH vibration mode.

 
  • 2O分子的这种现象是由于强的势能非谐性造成的;而H_2O_2分子除上述原因外;还与两个OH键振动模间的复杂耦合有关.
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