Conclusion The 3, 5-dinitrobenzoyl group was found to be a good leaving group at the anomeric position and O-glucopyranosides and oligosaccharides were stereoselectively synthesized in good yield.

• 结论3,5二硝基苯甲酰氧基作为良好的糖端基离去基用于寡糖的合成,具有反应条件温和、收率较高、立体选择性好的特点。