A novel ruthenium complex RuCl_2P(C_6H_5)_3_2-(R,R)-DPEN (DPEN=1,2-diphenylethylene- diamine) was synthesized and characterized by 1H and 31 P NMR. The ruthenium complex was applied to the asymmetric hydrogenation of acetonaphthone.
英
美
- 合成了(R；R)-1；2-二苯基乙二胺((R；R)-DPEN)、钌和三苯基膦的三元配合物RuCl2[P(C6H5)3]2-(R；R)-DPEN；并将其用于萘乙酮的不对称加氢反应.
